2504000134
  • Open Access
  • Review
Hydrogen-Doped Natural Gas and its Transportation Technology
  • Changfei Xu 1,   
  • Ruisheng Liu 2,   
  • Feibo Wang 1,   
  • Jinying Wu 1,   
  • Rui Wang 1,   
  • Zhuo Zhang 1, *

Received: 21 Aug 2024 | Revised: 23 Dec 2024 | Accepted: 24 Jan 2025 | Published: 28 Feb 2025

Abstract

With the continuous increase in energy consumption and the exacerbation of environmental problems, the energy transition is becoming increasingly urgent. Hydrogen, as a clean and zero-carbon energy source, has received extensive attention. Hydrogen-doped natural gas transportation technology has emerged as a promising solution to the challenge of large-scale hydrogen transportation. This article comprehensively reviews the development history of hydrogen doping technology in both China and around the world, and systematically analyzes the effects of hydrogen-doped natural gas on pipeline tubing, including the phenomena of hydrogen embrittlement, hydrogen permeation, leakage diffusion, and ignition explosion. The advantages of this technology, such as significant carbon emission reduction and enhanced energy utilization efficiency, are thoroughly examined. The challenges it faces, such as the elevated safety risks due to the flammability and explosiveness of hydrogen, the immaturity of production technologies, and the inadequacies in regulations and standards, are also meticulously pointed out. Looking ahead, in-depth technical research and development, the innovation of hydrogen production technologies, and the establishment of robust regulations and standards are crucial to facilitating the hydrogen-doped natural gas transportation technology to play a more prominent role in the energy field and to promoting the sustainable development of energy. Additionally, with the continuous innovation and breakthroughs in technology, it is expected that the hydrogen blending ratio can be further increased. For example, the hydrogen blending ratio in some regions may be raised to approximately 30% by 2030, thereby further reducing carbon emissions and accelerating the transformation of the energy structure towards clean and low-carbon.

References 

  • 1.
    Zuo, K.W. Exploration on the development prospect of natural gas industry under the background of dual carbon. In Proceedings of the Shanghai: 2023 Annual Meeting of China City Gas Association Standards Working Committee and Gas Safety Operation and Smart Construction Seminar, Shanghai, China, 26–29 July 2023; pp. 258–261.
  • 2.
    Qin, P.; Xu, H.; Liu, M.; Xiao, C.; Forrest, K.E.; Samuelsen, S.; Tarroja, B. Assessing concurrent effects of climate change on hydropower supply, electricity demand, and greenhouse gas emissions in the Upper Yangtze River Basin of China. Appl. Energy 2020, 279, 115694.
  • 3.
    Zhou, Y.; Zhou, H.J.; Xu, C.M. Exploration of the development path for the hydrogen energy. Chem. Ind. Eng. Prog. 2022, 41, 4587–4592.
  • 4.
    National Development and Reform Commission & National Energy Administration. Medium and Long Term Planning for the Development of Hydrogen Energy Industry (2021–2035); National Development and Reform Commission & National Energy Administration: Beijing, China, 2022.
  • 5.
    China New Energy Network. For the First Time in the World! Germany Will Achieve 20% Hydrogen Access; China New Energy Network: Beijing, China, 2019.
  • 6.
    Zhang, L.; Deng, H.T.; Sun, G.J.; Ning, C.; Sun, G.; Liu, W.; Sun, C.; Lan, X.; Lu, Y.; Jia, G.; et al. Research progress of natural gas follow-up hydrogen mixing technology. Mech. Eng. 2022, 44, 755–766.
  • 7.
    Anon. China’s long-distance hydrogen transport technology has achieved a breakthrough in hydrogen mixing ratio of 24%. Shanghai Energy Conserv. 2023, 4, 467.
  • 8.
    Anon. China’s first urban gas hydrogen mixing comprehensive experimental platform put into operation. Welded Pipe Tube 2024, 47, 38.
  • 9.
    Editorial Board of White Paper on China’s Hydrogen Energy and Fuel Cell Industry. White Paper on China’s Hydrogen Energy and Fuel Cell Industry (2019 Edition); China Hydrogen Alliance: Beijing, China, 2019.
  • 10.
    Chu, W.Y.; Qiao, L.J.; Li, J.X.; Su, Y.J.; Yan, Y.; Bai, Y.; Huang, H.Y. Hydrogen Embrittlement and Stress Corrosion Cracking; Science Press: Beijing, China, 2013; p. 116.
  • 11.
    Zhou, D.; Li, T.; Huang, D.; Wu, Y.; Huang, Z.; Xiao, W.; Wang, X. The experiment study to assess the impact of hydrogen blended natural gas on the tensile properties and damage mechanism of X80 pipeline steel. Int. J. Hydrogen Energy 2021, 46, 7402–7414.
  • 12.
    Dong, J.N.; Liu, Y.S.; Zhang, X.C. Influence Law of Hydrogen Pressure on Hydrogen Embrittlement Sensitivity of L80 Steel. Mater. Prot. 2022, 55, 53–59.
  • 13.
    Zhao, Q.; Xing, Y.Y.; Wang, X.Y. Research Status of Compatibility of Hydrogen-blended Natural Gas Pipeline. Mater. Rep. 2024, 38, 132–138.
  • 14.
    Robinson, S.L.; Stoltz, R.E. Hydrogen Effects in Metals; Bernstein, I.M., Thompson, A.W., Eds.; The Metallurgical Society of American Institute of Mining, Metallurgical, and Petroleum Engineers (AIME), Inc.: New York, NY, USA, 1981; p. 987.
  • 15.
    Alvaro, A.; Olden, V.; Macadre, A.; Akselsen, O.M. Hydrogen embrittlement susceptibility of a weld simulated X70 heat affected zone under H₂ pressure. Mater. Sci. Eng. A 2014, 597, 29–36.
  • 16.
    Nguyen, T.T.; Park, J.S.; Kim, W.S.; Nahm, S.H.; Beak, U.B. Environment hydrogen embrittlement of pipeline steel X70 under various gas mixture conditions with in situ small punch tests. Mater. Sci. Eng. 2020, 781, 139114.
  • 17.
    Shi, H.; Lyu, Y.; Tan, G.B. Feasibility study on pipeline transportation of hydrogen-blended natural gas. Nat. Gas Oil 2022, 40, 23–31.
  • 18.
    Nagumo, M. Fundamentals of Hydrogen Embrittlement; Springer: Singapore, 2016; p. 921.
  • 19.
    Han, Y.D.; Wang, R.Z.; Wang, H.; Xu, L.Y. Hydrogen embrittlement sensitivity of X100 pipeline steel under different pre–strain. Int. J. Hydrogen Energy 2019, 44, 22380–22393.
  • 20.
    Al-Mansour, M.; Alfantazi, A.M.; El-boujdaini, M. Sulfide stress cracking resistance of API–X100 high strength low alloy steel. Mater. Des. 2009, 30, 4088–4094.
  • 21.
    Dong, C.F.; Liu, Z.Y.; Li, X.G.; Cheng, Y.F. Effects of hydrogen-charging on the susceptibility of X100 pipeline steel to hydrogen–induced cracking. Int. J. Hydrogen Energy 2009, 34, 9879–9884.
  • 22.
    Nanninga, N.E.; Levy, Y.S.; Drexler, E.S.; Condon, R.T.; Stevenson, A.E.; Slifka, A.J. Comparison of hydrogen embrittlement in three pipeline steels in high pressure gaseous hydrogen environments. Corros. Sci. 2012, 59, 1–9.
  • 23.
    Cauwels, M.; Claeys, L.; Depover, T.; Verbeken, K. The hydrogen embrittlement sensitivity of duplex stainless steel with different phase fractions evaluated by in-situ mechanical testing. Frat. Integrità Strutt. 2020, 14, 449.
  • 24.
    Cheng, D.B.; Lin, J.G.; Wei, N.T. Review of hydrogen transmission pipeline technology development. Oil Gas Storage Transp. 2024, 43, 624–631.
  • 25.
    Li, J.H.; Xie, F.; Wang, D.; Ma, C.; Wu, M. Synergistic effect of sulfate-reducing bacteria and cathodic protection potential on hydrogen permeation and stress corrosion cracking of X100 steel in the maritime mud environment. Metall. Mater. Trans. A 2022, 53, 1682–1692.
  • 26.
    Yao, C.; Ming, H.; Chen, J.; Wang, J.; Han, E.H. Effect of cold deformation on the hydrogen permeation behavior of X65 pipeline steel. Coatings 2023, 13, 280.
  • 27.
    Zhu, J.L.; Zhou, H.; Li, Y.X.; Li, F.Y. Dynamic simulation of hydrogen blending natural gas transportation pipeline design. Nat. Gas Ind. 2021, 41, 132–142.
  • 28.
    Jia, W.L.; Wen, C.X.; Yang, M.; Huang, J.; Wu, X.; Li, C.J. Study on leakage and diffusion of hydrogen mixed natural gas in the valve chamber. Pet. New Energy 2021, 33, 75–82.
  • 29.
    Wang, X.; Xu, H.Y.; Cheng, D. Study on the leakage and diffusion behavior of hydrogen-blended natural gas pipeline under influence of obstacles. Chem. Saf. Environ. 2023, 36, 12–21.
  • 30.
    Shchelkin, K.I. Influence of tube roughness on the formation and detonation propagation in gas. J. Exp. Theor. Phys. 1940, 10, 823–827.
  • 31.
    Lee, J.H.S.; Moen, I.O. The mechanism of transition from deflagration to detonation in vapor cloud explosion. Prog. Energy Combust. Sci. 1980, 6, 359–389.
  • 32.
    Shepherd, J.E.; Lee, J.H.S. On the Transition from Deflagration to Detonation; Major Research Topics in Combustion. Springer: New York, NY, USA, 1992; pp. 439–487.
  • 33.
    Urtiew, P.A.; Oppenheim, A.K. Experimental observations of the transition to detonation in an explosive gas. Proceedings of the Royal Society of London. Ser. A Math. Phys. Sci. 1966, 295, 13–28.
  • 34.
    Ni, J.; Pan, J.; Jiang, C.; Chen, X.; Zhang, S. Effects of hydrogen-blending ratio on detonation characteristics of premixed methane-oxygen gas. Explos. Shock Waves 2020, 40, 25–33.
  • 35.
    Yu, J.; Zhang, H.; Jia, W.L. Numerical simulation of leakage and diffusion in hydrogen mixed natural gas transmission station. J. Southwest Pet. Univ. 2022, 44, 153–161.
  • 36.
    Wan, X.G.; Liu, W.; Fang, T.; Dai, H.; Cai, X.; Li, Q.; Wang, J.; Huang, Z.; Lan, X.; Chang, X. Effect of methane addition on hydrogen combustion and explosion characteristics. Mech. Eng. 2022, 44, 786–793.
  • 37.
    Zhang, G.; Xu, H.; Wu, D.; Yang, J.; Morsy, M.E.; Jangi, M.; Kim, W. Deep learning-driven analysis for cellular structure characteristics of spherical premixed hydrogen-air flames. Int. J. Hydrogen Energy 2024, 68, 63–73.
  • 38.
    Zhang, G.; Xu, H.; Wu, D.; Yang, J.; Morsy, M.E.; Jangi, M.; Cracknell, R. Quantitative three-dimensional reconstruction of cellular flame area for spherical hydrogen-air flames. Fuel 2024, 375, 132504.
  • 39.
    Witkowski, A.; Rusin, A.; Majkut, M.; Stolecka, K. Analysis of compression and transport of the methane/hydrogen mixture in existing natural gas pipelines. Int. J. Press. Vessel. Pip. 2018, 166, 24–34.
  • 40.
    Ma, J.; Liu, S.; Zhou, W.; Pan, X. Comparison of Hydrogen Transportation Methods for Hydrogen Refueling Station. J. Tongji Univ. 2008, 36, 615–619.
  • 41.
    Sierens, R.; Rosseel, E. Variable composition hydrogen/natural gas mixtures for increased engine efficiency and decreased emissions. J. Eng. Gas Turbines Power 2000, 122, 135–140.
  • 42.
    Ma, X.Y.; Huang, X.M.; Wu, C. Study on the influence of natural gas hydrogenation on combustion characteristics of domestic gas cooker. Renew. Energy 2018, 36, 1746−1751.
  • 43.
    Luo, Z.X.; Xu, H.C.; Yuan, M. Safety and emission performance test and evaluation of natural gas mixed with hydrogen combustion on domestic gas appliances. Chem. Eng. Oil Gas 2019, 48, 50−56.
  • 44.
    Xie, P.; Wu, Y.; Li, C.; Jia, W.; Zhang, H.; Wu, X. Research progress on pipeline transportation technology of hydrogen-mixed natural gas. Oil Gas Storage Transp. 2021, 40, 361–370.
  • 45.
    Shang, J.; Lu, Y.H.; Zheng, J.Y.; Sun, C.; Hua, Z.L.; Yu, W.T.; Zhang, Y.W. Research status-in-situ and key challenges in pipeline transportation of hydrogen-natural gas mixtures. Chem. Ind. Eng. Prog. 2021, 40, 5499–5505.
  • 46.
    Guandalini, G.; Colbertaldo, P.; Campanari, S. Dynamic modeling of natural gas quality within transport pipelines in presence of hydrogen injections. Appl. Energy 2017, 185, 1712–1723.
  • 47.
    Qiu, Y.; Zhou, S.; Gu, W.; Pan, G.; Chen, X. Application Prospect Analysis of Hydrogen Enriched Compressed Natural Gas Technologies Under the Target of Carbon Emission Peak and Carbon Neutrality. Proc. CSEE 2022, 42, 1301–1320.
Share this article:
How to Cite
Xu, C.; Liu, R.; Wang, F.; Wu, J.; Wang, R.; Zhang, Z. Hydrogen-Doped Natural Gas and its Transportation Technology. International Journal of Automotive Manufacturing and Materials 2025, 4 (1), 3. https://doi.org/10.53941/ijamm.2025.100003.
RIS
BibTex
Copyright & License
article copyright Image
Copyright (c) 2025 by the authors.