2606004235
  • Open Access
  • Article

Multi-Stress Coupling Aging of Silicon Heterojunction Modules: Encapsulant Degradation and Reliability Implications

  • Hong Luo 1,   
  • Yu Hu 2,*,   
  • Qi Deng 1,   
  • Xiaoying Ye 1,   
  • Yulin Zhang 2,   
  • Cheng Huang 1,   
  • Tao Chen 3,   
  • Lei Li 4,   
  • Wenzhu Liu 5,*,   
  • Jian Yu 1,*

Received: 08 May 2026 | Revised: 07 Jun 2026 | Accepted: 12 Jun 2026 | Published: 17 Jul 2026

Abstract

The long-term reliability of silicon heterojunction (SHJ) photovoltaic modules is pivotal for their outdoor deployment and commercial viability. However, prevailing reliability assessments often rely on single-factor aging tests, which inadequately represent the synergistic stresses encountered in real-world climates. This study emphasizes the critical necessity of multi-stress coupling aging for a true durability evaluation. We conducted comparative 1000-h aging tests on SHJ modules and three types of encapsulants (EVA, dsEVA, and POE) under both damp-heat (DH) and UV-damp-heat (UVDH) coupling conditions. The results demonstrated that degradation mechanisms and severity are profoundly amplified under coupled stresses. Under UVDH, massive moisture ingress caused deacetylation in EVA/dsEVA, generating acetic acid that corroded solar cells, solder ribbons, and electrodes. Conversely, POE films suffered a severe loss of interfacial adhesion, leading to pronounced delamination. A systematic analysis of optical, mechanical, and chemical property changes in the films revealed a direct correlation between encapsulant degradation and module performance loss. Critically, the degradation under UVDH coupling conditions was significantly more severe than under DH alone, highlighting the synergistic acceleration effect of combined ultraviolet radiation and humidity. This work conclusively shows that multi-stress coupling tests are imperative for an accurate reliability assessment. It is recommended to integrate such coupled-aging protocols into standard testing regimes to better predict module lifetime, guide encapsulant material optimization, and ensure sustainable field performance.

Graphical Abstract

References 

  • 1.

    Photovoltaics Equipment. International Technology Roadmap for Photovoltaic (ITRPV): 2024 Results, 16th ed.; VDMA: Frankfurt/Main, Germany, 2025. Available online: https://www.vdma.eu/de/international-technology-roadmap-photovoltaic (accessed on 7 May 2026).

  • 2.

    Addonizio, M.; Antonaia, A. Textured p-type crystalline silicon surfaces obtained by multi-step plasma process for SHJ solar cells. Vacuum 2023, 215, 112284. https://doi.org/10.1016/j.vacuum.2023.112284.

  • 3.

    Andreani, L.C.; Bozzola, A.; Kowalczewski, P.; et al. Silicon solar cells: Toward the efficiency limits. Adv. Phys.-X 2019, 4, 1548305. https://doi.org/10.1080/23746149.2018.1548305.

  • 4.

    Bashiri, H.; Karami, M.A.; Nejad, S.M. An analytical approach for modeling of high-efficiency crystalline silicon solar cells with homo–hetero junctions. Mater. Sci. Semicond. Process 2020, 111, 104960. https://doi.org/10.1016/j.mssp.2020.104960.

  • 5.

    Bai, Y.; Zhao, Y.; Li, J.; et al. Lower levelized cost of energy achievement of silicon heterojunction solar modules with low water vapor transmission rate encapsulants. Energy Technol. 2023, 11, 2201466. https://doi.org/10.1002/ente.202201466.

  • 6.

    Green, M.A.; Dunlop, E.D.; Yoshita, M.; et al. Solar cell efficiency tables (version 66). Prog. Photovolt. 2025, 33, 795–810. https://doi.org/10.1002/pip.3919.

  • 7.

    Arriaga Arruti, O.; Gnocchi, L.; Jeangros, Q.; et al. Potential-induced degradation in bifacial silicon heterojunction solar modules: Insights and mitigation strategies. Prog. Photovolt. 2024, 32, 304–316. https://doi.org/10.1002/pip.3765.

  • 8.

    Li, X.; Yang, Y.; Jiang, K.; et al. Potential-free sodium-induced degradation of silicon heterojunction solar cells. Prog. Photovolt. 2023, 31, 939–948. https://doi.org/10.1002/pip.3698.

  • 9.

    Ye, H.; Huang, S.; Qian, C.; et al. Short wavelength photons destroying Si-H bonds and its influence on high-efficiency silicon solar cells and modules. Sol. RRL 2023, 7, 2300334. https://doi.org/10.1002/solr.202300334.

  • 10.

    Sen, C.; Wang, H.; Wu, X.; et al. Four failure modes in silicon heterojunction glass-backsheet modules. Sol. Energy Mater. Sol. Cells 2023, 257, 112358. https://doi.org/10.1016/j.solmat.2023.112358.

  • 11.

    Yu, J.; Bai, Y.; Qiu, Q.; et al. Reliability of transparent conductive oxide in ambient acid and implications for silicon solar cells. eScience 2024, 4, 100241. https://doi.org/10.1016/j.esci.2024.100241.

  • 12.

    Deng, Q.; Ye, H.; Huang, S.; et al. Mechanism of photon-induced performance changes in silicon heterojunction solar cells. Sci. China-Mater. 2024, 67, 2873–2879. https://doi.org/10.1007/s40843-024-2997-7.

  • 13.

    Bai, Y.; Zhang, Y.; Luo, H.; et al. Degradation-free high-efficiency fluoride-coating solar cells via precision interface engineering. Prog. Photovolt. 2025, 33, 1260–1270. https://doi.org/10.1002/pip.70018.

  • 14.

    Damo, U.; Ozoegwu, C.G.; Ogbonnaya, C.; et al. Effects of light, heat and relative humidity on the accelerated testing of photovoltaic degradation using Arrhenius model. Sol. Energy 2023, 250, 335–346. https://doi.org/10.1016/j.solener.2023.01.002.

  • 15.

    Gaddam, S.K.; Pothu, R.; Boddula, R. Advanced polymer encapsulates for photovoltaic devices—A review. J. Materiomics 2021, 7, 920–928. https://doi.org/10.1016/j.jmat.2021.04.004.

  • 16.

    Meena, R.; Pareek, A.; Gupta, R. A comprehensive Review on interfacial delamination in photovoltaic modules. Renew. Sust. Energy Rev. 2024, 189, 113944. https://doi.org/10.1016/j.rser.2023.113944.

  • 17.

    Ren, J.; Zhao, W.; Shi, J.; et al. Predicting the lifetime of HJT modules towards the outdoor real-world environment. Sol. Energy Mater. Sol. Cells 2024, 272, 112885. https://doi.org/10.1016/j.solmat.2024.112885.

  • 18.

    Razzaq, S.; Wei, L.; Jiao, R.; et al. Enhancing UV light stability in commercial silicon HJT solar cells and modules. Sol. Energy 2025, 298, 113735. https://doi.org/10.1016/j.solener.2025.113735.

  • 19.

    Liu, W.; Zhang, L.; Yang, X.; et al. Damp-heat-stable, high-efficiency, industrial-size silicon heterojunction solar cells. Joule 2020, 4, 913–927. https://doi.org/10.1016/j.joule.2020.03.003.

  • 20.

    Park, H.; Jeong, J.; Shin, E.; et al. A reliability study of silicon heterojunction photovoltaic modules exposed to damp heat testing. Microelectron. Eng. 2019, 216, 111081. https://doi.org/10.1016/j.mee.2019.111081.

  • 21.

    Segbefia, O.K.; Imenes, A.G.; Saetre, T.O. Moisture ingress in photovoltaic modules: A review. Sol. Energy 2021, 224, 889–906. https://doi.org/10.1016/j.solener.2021.06.055.

  • 22.

    Zeng, F.; He, Y.; Xu, S.; et al. Accelerated degradation of PET-based photovoltaic backsheets under UV and acetic acid exposure. Polymer 2024, 312, 127671. https://doi.org/10.1016/j.polymer.2024.127671.

  • 23.

    Kivambe, M.; Abdallah, A.; Figgis, B.; et al. Comprehensive assessment of performance and reliability of PERC, TOPCon and SHJ modules in desert climates. Sol. Energy 2025, 295, 113555. https://doi.org/10.1016/j.solener.2025.113555.

  • 24.

    Frischholz, Y.; Schilt, U.; Sharma, V.; et al. Confirmation of the power gain for solar photovoltaic systems in alpine areas and across scales. Front. Energy Res. 2024, 12, 1372680. https://doi.org/10.3389/fenrg.2024.1372680.

  • 25.

    Tsuchida, S.; Tsuno, Y.; Sato, D.; et al. Power generation characteristics of vertical bifacial photovoltaic arrays in heavy snow regions. EPJ Photovolt. 2024, 15, 32. https://doi.org/10.1051/epjpv/2024029.

  • 26.

    Barretta, C.; Macher, A.E.; Ascencio-Vásquez, J.; et al. Degradation of crystalline silicon photovoltaic modules installed in different climates. In Proceedings of the 2022 IEEE 49th Photovoltaics Specialists Conference (PVSC), Philadelphia, PA, USA, 5–10 June 2022; pp. 0680–0682. https://doi.org/10.1109/PVSC48317.2022.9938590.

  • 27.

    Santhakumari, M.; Sagar, N. A review of the environmental factors degrading the performance of silicon wafer-based photovoltaic modules: Failure detection methods and essential mitigation techniques. Renew. Sust. Energy Rev. 2019, 110, 83–100. https://doi.org/10.1016/j.rser.2019.04.024.

  • 28.

    Tsanakas, J.; Babics, M.; Mezzasalma, F.; et al. Long-term field degradation of crystalline-silicon PV modules: Insights from fifteen years of monitoring and forensic analysis. EPJ Photovolt. 2026, 17, 14. https://doi.org/10.1051/epjpv/2026006.

  • 29.

    Uličná, S.; Sinha, A.; Miller, D.C.; et al. PV encapsulant formulations and stress test conditions influence dominant degradation mechanisms. Sol. Energy Mater. Sol. Cells 2023, 255, 112319. https://doi.org/10.1016/j.solmat.2023.112319.

  • 30.

    Liu, K.; Miller, D.C.; Bosco, N.; et al. Advancing steady-state and sequenced accelerated aging for assessing the adhesion degradation of contemporary encapsulants. In Proceedings of the 2025 IEEE 53rd Photovoltaic Specialists Conference (PVSC), Montreal, QC, Canada, 8–13 June 2025; pp. 0738–0743. https://doi.org/10.1109/PVSC59419.2025.11133400.

  • 31.

    Säckl, G.; Wallner, G.M.; Duchoslav, J.; et al. Advanced analysis of ethylene vinyl acetate copolymer materials for photovoltaic modules. Polym. Test 2024, 132, 108381. https://doi.org/10.1016/j.polymertesting.2024.108381.

  • 32.

    Lee, K.; Kim, D.; Kim, S.H.; et al. Improving the physical properties of polyolefin elastomer encapsulants by radical initiators for reliable photovoltaic modules. Polym. Test 2025, 151, 108954. https://doi.org/10.1016/j.polymertesting.2025.108954.

  • 33.

    Sun, Z.; Xia, Z.; Yan, D.; et al. Industrial-scale silicon heterojunction photovoltaic module towards 25% efficiency enabled by high-quantum-yield CaSrSiO4: Ce3+ inorganic downshifting materials. Prog. Photovolt. 2025, 33, 678–688. https://doi.org/10.1002/pip.3908.

  • 34.

    Pern, F.; Czanderna, A.; Emery, K.; et al. Weathering degradation of EVA encapsulant and the effect of its yellowing on solar cell efficiency. In Proceedings of the The Conference Record of the Twenty-Second IEEE Photovoltaic Specialists Conference-1991, Las Vegas, NV, USA, 7–11 October 1991; pp. 557–561. https://doi.org/10.1109/PVSC.1991.169275.

  • 35.

    Pern, F.; Czanderna, A. Characterization of ethylene vinyl acetate (EVA) encapsulant: Effects of thermal processing and weathering degradation on its discoloration. Sol. Energy Mater. Sol. Cells 1992, 25, 3–23. https://doi.org/10.1016/0927-0248(92)90013-F.

  • 36.

    Fiandra, V.; Sannino, L.; Andreozzi, C.; et al. New PV encapsulants: Assessment of change in optical and thermal properties and chemical degradation after UV aging. Polym. Degrad. Stab. 2024, 220, 110643. https://doi.org/10.1016/j.polymdegradstab.2023.110643.

  • 37.

    Jin, J.; Chen, S.; Zhang, J. UV aging behaviour of ethylene-vinyl acetate copolymers (EVA) with different vinyl acetate contents. Polym. Degrad. Stab. 2010, 95, 725–732. https://doi.org/10.1016/j.polymdegradstab.2010.02.020.

  • 38.

    Hasan, A.A.; Ahmed Alkahtani, A.; Shahahmadi, S.A.; et al. Delamination-and electromigration-related failures in solar panels—A review. Sustainability 2021, 13, 6882. https://doi.org/10.3390/su13126882.

  • 39.

    Barretta, C.; Oreski, G.; Feldbacher, S.; et al. Comparison of degradation behavior of newly developed encapsulation materials for photovoltaic applications under different artificial ageing tests. Polymers 2021, 13, 271. https://doi.org/10.3390/polym13020271.

  • 40.

    Adothu, B.; Bhatt, P.; Chattopadhyay, S.; et al. Newly developed thermoplastic polyolefin encapsulant–A potential candidate for crystalline silicon photovoltaic modules encapsulation. Sol. Energy 2019, 194, 581–588. https://doi.org/10.1016/j.solener.2019.11.018.

  • 41.

    Hou, J.; Ma, D.; Zhang, Z.; et al. Visible-light-driven Fe-catalyzed alkylation for synthesizing functionalized polyolefin elastomers as advanced encapsulants in photovoltaic modules. React. Funct. Polym. 2024, 205, 106072. https://doi.org/10.1016/j.reactfunctpolym.2024.106072.

  • 42.

    Xie, N.; Zhang, Y.; Wang, S.; et al. Encapsulation Films for Silicon Solar Cells: Multifunctional Polyolefin Elastomeric Films Fabricated by In Situ Grafting a Eu3+ Complex. ACS Appl. Polym. Mater. 2025, 7, 5573–5583. https://doi.org/10.1021/acsapm.5c00455.

Share this article:
How to Cite
Luo, H.; Hu, Y.; Deng, Q.; Ye, X.; Zhang, Y.; Huang, C.; Chen, T.; Li, L.; Liu, W.; Yu, J. Multi-Stress Coupling Aging of Silicon Heterojunction Modules: Encapsulant Degradation and Reliability Implications. Materials Matter 2026, 1 (1), 4.
RIS
BibTex
Copyright & License
article copyright Image
Copyright (c) 2026 by the authors.