2609005139
  • Open Access
  • Article

Disturbance and Natural Recovery of Surface Water Quality in a Semi-Industrial Gold Mining District (Eséka, Central Cameroon): A Tropical Earth System Perspective

  • Irma Gaelle Awono 1,   
  • Moïse Welba 2,   
  • Rel Dechangue Tatou 1,   
  • Elisé Sababa 2,*,   
  • Vincent Laurent Onana 1,2

Received: 25 Jun 2026 | Revised: 18 Aug 2026 | Accepted: 04 Sep 2026 | Published: 10 Sep 2026

Highlights

  • Semi-industrial gold mining in Eséka significantly degrades surface water quality
  • High concentrations of Pb, Cd, As, Cr, and Co exceed WHO drinking water guidelines
  • Water Quality Index (WQI) values range from good to very poor
  • Ingestion is the dominant exposure pathway for heavy metals
  • Older abandoned mining sites show natural restoration of water quality

Abstract

Surface water quality in the Eséka gold district (Central Cameroon) was investigated to understand the coupled impacts of semi-industrial mining and tropical Earth surface processes. Physicochemical parameters and heavy metal concentrations were quantified across a chronosequence of actively mined and abandoned sites. Mining activities significantly lowered water pH, increased water temperature, and reduced dissolved oxygen concentrations. High concentrations of Pb, Cd, As, and Cr are linked to sulfide oxidation and leaching of host minerals (e.g., galena, arsenopyrite) in waste rock. The Water Quality Index (WQI) ranges from good (at older, abandoned sites) to very poor (at active mines), suggesting that natural recovery processes may improve water quality at some mining sites in humid tropical environments. Health risk assessment identified ingestion as the primary exposure pathway. The cumulative Hazard Index (HI) for children was 29.55, indicating significant non-carcinogenic risk resulting from the combined contributions of Pb, As, Co, and Cr. Adults face elevated risks primarily from As and Co. These findings provide a conceptual model of mining-induced disturbance and natural attenuation in tropical catchments, with implications for global change remediation strategies and sustainable development in resource-dependent regions.

Graphical Abstract

References 

  • 1.

    FAO. Water Overview; Food and Agriculture Organization of the United Nations: Rome, Italy, 2026.

  • 2.

    Normatov, P.; Armstrong, R.; Normatov, I.; et al. Monitoring extreme water factors and studying the anthropogenic load of industrial objects on water quality in the Zeravshan River basin. Russ. Meteorol. Hydrol. 2015, 40, 347–354.

  • 3.

    Salvarredy Aranguren, M.M. Contamination en métaux lourds des eaux de surface et des sédiments du Val de Milluni (Andes boliviennes) par des déchets miniers: Approches géochimiques, minéralogiques et hydrochimiques. Ph.D. Thesis, Université Toulouse III–Paul Sabatier, Toulouse, France, 2008; 371p + 86p.

  • 4.

    Singh, V.; Singh, N.; Rai, S.N.; et al. Heavy metal contamination in the aquatic ecosystem: toxicity and its remediation using eco-friendly approaches. Toxics 2023, 11, 147.

  • 5.

    Ngoa Manga, E.S.; Ekoa Bessa, A.Z.; Ayissi Mbomo, R.E.; et al. Evaluation of surface water contamination and its impacts on health in the mining districts of Kambélé and Bétaré-Oya (Eastern-Cameroon). Heliyon 2024, 10, e29189.

  • 6.

    Sababa, E.; Ndong Bidzan, F.; Thena, N.; et al. Evaluation des éléments traces métalliques (Cr, As, Pb, Zn et Cd) dans les eaux de surface du bassin versant du Lom, Est Cameroun: Impact de l'exploitation semi-industrielle de l'or. Sci. Technol. Dev. 2018, 20, 1–10.

  • 7.

    Sababa, E.; Mbesse, C.O.; Wandji Mouko, C.N.; et al. Geochemistry of stream sediments from Eséka area (SW Cameroon): implications for surface process assessment and precious metals (Au, Pd, and Pt) exploration. J. Sediment. Environ. 2022, 7, 43–66.

  • 8.

    Atangana, M.S.B.; Ndam Ngoupayou, J.R.; Deliege, J.F. Hydrogeochemistry and Mercury Contamination of Surface Water in the Lom Gold Basin (East Cameroon): Water Quality Index, Multivariate Statistical Analysis and Spatial Interpolation. Water 2023, 15, 2502.

  • 9.

    Kouankap Nono, G.D.; Tah Bong, C.; Wotchoko, P.; et al. Artisanal gold mining in Batouri area, East Cameroon: Impacts on the mining population and their environment. J. Geol. Min. Res. 2017, 9, 1–8.

  • 10.

    Mambou Ngueyep, L.L.; Takougang Kingni, S.; Ayiwouo Ngounouno, M.; et al. The impact of gold mining exploitation on the physicochemical quality of water: case of Batouri (Cameroon). Int. J. Energy Water Resour. 2021, 5, 159–173.

  • 11.

    Rakotondrabe, F.; Ngoupayou, J.R.N.; Mfonka, Z.; et al. Assessment of surface water quality of Bétaré-Oya gold mining area (East-Cameroon). J. Water Resour. Prot. 2017, 9, 960–984.

  • 12.

    Owona, S.; Schulz, B.; Minyem, D.; et al. Eburnean/Trans-Amazonian orogeny in the Nyong complex of southwestern Cameroon: Meta-basite geochemistry and metamorphic petrology. J. Afr. Earth Sci. 2022, 190, 104515.

  • 13.

    Feybesse, J.L.; Johan, V.; Maurizot, P.; et al. Evolution tectonométamorphique libérienne et éburnéenne de la partie NW du craton zaïrois (SW Cameroun). In Proceedings of the 14th Colloquium on African Geology, Berlin, Germany, 18–22 August 1987; pp. 9–12.

  • 14.

    Toteu, S.F.; Penaye, J.; Djomani, Y.P. Geodynamic evolution of the Pan-African belt in central Africa with special reference to Cameroon. Can. J. Earth Sci. 2004, 41, 73–85.

  • 15.

    Champetier de Ribes, G.; Aubague, M. Carte Géologique de Reconnaissance à l'echelle du 1/500000; Royal Museum for Central Africa: Tervuren, Belgium, 1956; 35p.

  • 16.

    Eymery, F.; Choubert, J.; Lepot, B.; et al. Guide Technique OpéRationnel: Pratiques D'éChantillonnage Et De Conditionnement en Vue De La Recherche De Micropolluants Prioritaires Et éMergents en Assainissement Collectif Et Industriel, Première version ed.; Irstea/Cemagref: Lyon, France, 2011; 85p.

  • 17.

    American Public Health Association (APHA). Standard Methods for the Examination of Water and Sewage; American Public Health Association: Washington, DC, USA, 1912. pp. 11–15.

  • 18.

    Rodier, J.; Legube, B.; Merlet, N. L'analyse De L'eau, 9th ed.; Dunod: Paris, France, 2009; 1579p.

  • 19.

    N'guessan, Y.M.; Wango, T.E.; Adopo, K.L.; et al. Geochemical characteristics of surface waters in an agricultural environment: Case of Gascogne catchments (Midi Pyrénées Region, S-W France). Int. J. Innov. Appl. Stud. 2016, 17, 394–406.

  • 20.

    Horton, R.K. An index number system for rating water quality. J. Water Pollut. Control Fed. 1965, 37, 300–306.

  • 21.

    Brown, R.; McClelland, N.; Deininger, R.; et al. A water quality index—Do we dare? Water Sew. Work. 1970, 117, 339–343.

  • 22.

    WHO. Guidelines for Drinking-Water Quality, 4th ed.; World Health Organization: Geneva, Switzerland, 2011; 518p.

  • 23.

    Sahu, P.; Sikdar, P.K. Hydrochemical framework of the aquifer in and around East Kolkata Wetlands, West Bengal, India. Environ. Geol. 2008, 55, 823–835.

  • 24.

    Asomaku, S.O. Quality assessment of groundwater sourced from nearby abandoned landfills from Industrial City in Nigeria: Water pollution indices approach. HydroResearch 2023, 6, 130–137.

  • 25.

    Mohan, S.V.; Nithila, P.; Reddy, S.J. Estimation of heavy metals in drinking water and development of heavy metal pollution index. J. Environ. Sci. Health. Part A Environ. Sci. Eng. Toxicol. 1996, 31, 283–289.

  • 26.

    Ojekunle, O.Z.; Ojekunle, O.V.; Adeyemi, A.A.; et al. Evaluation of surface water quality indices and ecological risk assessment for heavy metals in scrap yard neighbourhood. SpringerPlus 2016, 5, 560.

  • 27.

    Okanlawon, M.O.; Olasehinde, P.I.; Abdullahi, I.N.; et al. Water quality determination around gold and manganese mining area using metal pollution index and water quality index in South-Western part of Tegina Sheet 142 North Central Nigeria. Int. J. Innov. Res. Dev. 2017, 6, 40–49.

  • 28.

    Hakanson, L. An ecological risk index for aquatic pollution control. A sedimentological approach. Water Res. 1980, 14, 975–1001.

  • 29.

    Tomlinson, D.L.; Wilson, J.G.; Harris, C.R.; et al. Problems in the assessment of heavy-metal levels in estuaries and the formation of a pollution index. Helgoländer Meeresunters. 1980, 33, 566–575.

  • 30.

    Khan, S.; Cao, Q.; Zheng, Y.; et al. Health risks of heavy metals in contaminated soils and food crops irrigated with wastewater in Beijing, China. Environ. Pollut. 2008, 152, 686–692.

  • 31.

    Cabrera, F.; Clemente, L.; Díaz Barrientos, E.; et al. Heavy metal pollution of soils affected by the Guadiamar toxic flood. Sci. Total Environ. 1999, 242, 117–129.

  • 32.

    US-EPA (United States Environmental Protection Agency). Risk Assessment: Regional Screening Levels (RSLs)—Equations; US-EPA: Washington, DC, USA, 2023; pp. 1–6.

  • 33.

    Mall, I.; Diaw, M.; Dieng, N.M.; et al. Evaluation of water resources quality in Sabodala gold mining region and its surrounding area (Senegal). J. Water Resour. Prot. 2015, 7, 247–263.

  • 34.

    Foto Menbohan, S.; Tchakonte, S.; Ajeagah Gideon, A.; et al. Water quality assessment using benthic macroinvertebrates in a periurban stream (Cameroon). Int. J. Biotechnol. 2013, 2, 91–104.

  • 35.

    Davies-Colley, R.J.; Smith, D.G. Turbidity suspended sediment, and water clarity: A review. J. Am. Water Resour. Assoc. 2001, 37, 1085–1101.

  • 36.

    Sababa, E.; Ekoa Bessa, A.Z. Heavy Metals Signature in Stream Sediments at Eséka Gold District, Central Africa: A Pre-mining Environmental Assessment. Chem. Afr. 2022, 5, 413–430.

  • 37.

    Al-Falal, A.N.A.; Elsayed, S.; El Fadaly, E.A.; et al. Aquatic system assessment of potentially toxic elements in El Manzala Lake, Egypt: A statistical and machine learning approach. Results Eng. 2025, 26, 105027.

  • 38.

    Byrne, P.; Yendell, A.; Frau, I.; et al. Identification and prioritisation of mine pollution sources in a temperate watershed using tracer injection and synoptic sampling. Mine Water Environ. 2021, 40, 980–993.

  • 39.

    Abende Sayom, Y.R.; Mefomdjo, B.F.; Tarkwa, J.B.; et al. Comprehensive Water Quality and Heavy Metal Pollution Assessment of the Lom River in Bekao Gold Mining Sites (Adamawa-Cameroon) Using the Pollution Indices and Multivariate Statistical Approach. Water Air Soil Pollut. 2023, 234, 653.

  • 40.

    Samba Assomo, P.; Bouba, L.; Kouayep Lawou, S.; et al. Physico-chemical characterization and metallic trace element concentrations in surface waters of East Cameroon: case studies of the Tidamba watercourse in Bertoua and the Kambele mining basin in Batouri. Arab. J. Geosci. 2023, 16, 252.

  • 41.

    Sparks, D.L. Fundamentals of soil chemistry. In Encyclopedia of Water: Science, Technology, and Society; John Wiley & Sons, Inc.: Hoboken, NJ, USA, 2019; pp. 1–11.

  • 42.

    Wong, H.K.T.; Gauthier, A.; Nriagu, J.O. Dispersion and toxicity of metals from abandoned gold mine tailings at Goldenville, Nova Scotia, Canada. Sci. Total Environ. 1999, 228, 35–47.

  • 43.

    Yang, M.; Fu, W.; Chen, H.; et al. The impacts of molybdenum exploration on Cd and Zn contents in surface water: Evidence from a molybdenum mine in the Xiaoqinling Mountains. Minerals 2023, 13, 1207.

  • 44.

    Serfor-Armah, Y.; Nyarko, B.J.B.; Dampare, S.B.; et al. Levels of Arsenic and Antimony in Water and Sediment from Prestea, A Gold Mining Town in Ghana and its Environs. Water Air Soil Pollut. 2006, 175, 181–192.

  • 45.

    Mefomdjo Fotie, B.; Boukari, H.; Daou, I.E.; et al. Physicochemical Characterisation of Water and Sediment of the Semimechanized Artisanal Gold Mining Environment of the Béké Locality. Appl. Environ. Soil Sci. 2024, 2024, 6888252.

  • 46.

    Corkhill, C.L.; Vaughan, D.J. Arsenopyrite oxidation—A review. Appl Geochem. 2009, 24, 2342–2361.

  • 47.

    Gad, M.; Saleh, A.H.; Hussein, H.; et al. Appraisal of surface water quality of Nile River using water quality indices, spectral signature and multivariate modeling. Water 2022, 14, 1131.

  • 48.

    Nga Essomba Tsoungui, P.; Ganno, S.; Tanko Njiosseu, E.L.; et al. Geochemical constraints on the origin and tectonic setting of the serpentinized peridotites from the Paleoproterozoic Nyong series, Eséka area, SW Cameroon. Acta Geochim. 2020, 39, 404–422.

  • 49.

    Appleton, J.; Williams, T.; Orbea, H.; et al. Fluvial contamination associated with artisanal gold mining in the Ponce Enriquez, Portovelo-Zaruma and Nambija areas, Ecuador. Water Air Soil Pollut. 2001, 131, 19–39.

  • 50.

    George, L.L.; Cook, N.J.; Ciobanu, C.L.; et al. Partitioning of trace elements in co-crystallized sphalerite–galena–chalcopyrite hydrothermal ores. Ore Geol. Rev. 2016, 77, 97–116.

  • 51.

    Ndema Mbongué, J.L.; Sigué, C.; Mbowou Ngantche, I.F.; et al. Potentially toxic metals contamination in stream sediments of Mbal area (Pan-African fold belt, Cameroon). Discov. Geosci. 2024, 2, 15.

  • 52.

    Dairou, B.; Ngo Bidjeck Bondje, L.M.; Ndjigui, P.D. Assessment of pollution and ecological risk associated with heavy metals in sediments from the rivers of Batouri gold mining area (East Cameroon): geochemical and statistical approaches. J. Sediment. Environ. 2025, 10, 159–171.

  • 53.

    Diab, D.A.; Marcel, J.; Aguiza Abai, E.; et al. Hydrogeological Impact of Gold Mining, Contaminant Flow Patterns and Groundwater Quality Assessment in the Kambele Mining Area, Eastern Part of Cameroon. J. Environ. Prot. 2025, 16, 384–402.

  • 54.

    Ayiwouo, M.N.; Yamgouot, F.N.; Mambou, L.L.N.; et al. Impact of gold mining on the water quality of the Lom River, Gankombol, Cameroon. Heliyon 2022, 8, e12452.

  • 55.

    Kazapoe, R.W.; Kwayisi, D.; Alidu, S.; et al. Source-specific probabilistic health risk assessment of potentially toxic elements in soils from a mining area using Monte Carlo simulation: A case study from southwestern Ghana. Ecol. Indic. 2025, 174, 113376.

  • 56.

    Sun, L.; Wang, X.; Liu, Y.; et al. Improved model for human health risk assessment of soil heavy metal(loid)s in a mining area of southeastern China. Ecotoxicol. Environ. Saf. 2025, 306, 119312.

  • 57.

    Yu, J.; Li, J.J.; Han, R.B.; et al. Health Risk Assessment of Heavy Metals in Mining Soils and Analysis of Influencing Factors. Huan Jing Ke Xue 2026, 47, 1316–1328.

  • 58.

    Yuan, B.; Du, P.; Chen, J.; et al. Two-dimensional Monte Carlo simulation improves source-specific health risk assessment accuracy of soil heavy metals in a legacy mining region. J. Hazard. Mater. 2025, 496, 139190.

  • 59.

    Zhou, Y.; Ding, D.; Li, X.; et al. The integrating eco-health risk assessment and driving factors for risks of heavy metals in soils from an open-pit lead-zinc mine area. Ecotoxicol. Environ. Saf. 2026, 321, 120348.

  • 60.

    Li, H.; Yao, J.; Min, N.; et al. Considering the bioavailability and bioaccessibility of metal(loid)s for risk assessment of soils affected by different non-ferrous metal activities in Southwest China. J. Hazard. Mater. 2024, 472, 134527.

  • 61.

    Liu, S.; Li, Y.; Zhan, C.; et al. Assessing bioavailability risks of heavy metals in polymetallic mining regions: A comprehensive analysis of soils with varied land uses. Environ. Monit. Assess. 2024, 196, 975.

  • 62.

    Ata, A.A.E.S.M.; Aly, M.H.; Hussein, H.; et al. Hydrogeochemical characteristics and air quality risks associated with gold mining operations in Egypt using geochemical modeling and risk indices. Heliyon 2024, 10, e31086.

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Awono, I. G.; Welba, M.; Tatou, R. D.; Sababa, E.; Onana, V. L. Disturbance and Natural Recovery of Surface Water Quality in a Semi-Industrial Gold Mining District (Eséka, Central Cameroon): A Tropical Earth System Perspective. Global Environmental Science 2026, 2 (3), 372–391. https://doi.org/10.53941/ges.2026.100024.
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