Growing concerns have been raised regarding the potential environmental impacts of seawater desalination. While numerous studies have employed Life Cycle Assessment (LCA) to evaluate impacts, these efforts have primarily focused on quantifying the carbon footprint (CF) of seawater desalination; a tailored methodology for water footprint (WF) quantification remains notably lacking. To address this gap, this study presents a comprehensive WF assessment method for desalination plants, including system boundary definition, process-level inventory analysis, a quantification framework, and results interpretation. The methodology was applied to case studies on Reverse Osmosis (RO) plant. From a water scarcity footprint (WSF) perspective, the RO seawater desalination system consumes only 0.0366 m3 of freshwater to produce 1 m3 of product water. Furthermore, two methods assessed the water degradation footprint (WDF). The critical dilution volume method yielded a WDF of 0 m3 H2O eq for both plants, indicating no dilution was needed. Using the equivalency factor method, the acidification and eutrophication footprints for RO brine were 2.74 × 10−3 kg SO2 eq/m3 and 9.81 × 10−4 kg PO43− eq/m3, respectively. Additionally, analysis showed that electricity and steam consumption are the main drivers of water scarcity in RO and MED plants, respectively, with slight seasonal variations. This study resolves long-standing ambiguities in WDF accounting by clarifying the distinct application conditions of the critical dilution volume method and the equivalency factor method, while providing transparent, step-by-step calculation procedures often omitted in previous studies; practically, it offers industrial managers and environmental regulators a robust tool to precisely identify water-intensive hotspots.



